Plus, as the heat is transferred to the liquid, there would be some latent heat of vaporization as the heat is absorbed further cooling the liquid.
I stand corrected. Should have said "latent heat of vaporization as the heat is absorbed, further cooling the surface of the tank (not the liquid in the tank)." You are absolutely correct as the vaporization process results in no increase in bulk temperature of the liquid but rather an increase in gas pressure, albeit very small for the values in this case (second order effects excluded).
My qualification sign off on the "pressurizer system" on a S5W/S3G Core 3 submarine nuclear power plant would have pulled his signature from my card. In fact, the 1st Class Petty Officer signing off my qual card at prototype corrected me on this too before he signed off on my card. The principle involved here is exactly the one that led to the misconception of the status of the liquid level in the pressurizer at Three Mile Island that then precipitated in manually securing High Pressure Coolant Injection that ultimately led to shifting the bubble from the pressurizer to the core and resulted in melting 1/3 of the core at Three Mile Island.
Not withstanding that, you should be able to tell a noticeable difference in the temperature of the tank above and below the liquid level line even with your hand, let a lone an IR Gun.