There are both galvanic and stray current possibilities.
OK, we're on a little more solid ground here looking for stray voltage, although it's very unlikely you've got galvanic current in there as the shell of the hex. is usually of the same material as the tubes to avoid galvanic corrosion and its associated current.
It is one of the reasons distilled water is used. Make sure you have good, low resistance grounds.
Maybe I'm not correctly following you here but everything around the hex. is well grounded even if the coolant is drained from he hex. I'm going to presume the bolts holding the hex. to the block are the major conductors for grounding the hex.
As far as using distilled water in the 50/50 coolant, using distilled water will actually decrease (however slightly) the conductivity of the coolant due to the LACK of total dissolved solids (TDS) as compared to tap water. And this of course doesn't amount to a hill of beans because the hex. is well grounded. Distilled water is preferred because it lacks the TDS such as Mg and Ca which tap water contains and precipitate out on the heat exchange surfaces over time.
As you previously pointed out, the only time you would expect to see V in a hex. is when you accidentally touch a (+) wire to the casing.
It is not impossible to have a voltage due to a wiring error (nothing to do with coolant condition dirrectly). I've seen this when electric fans on cars are replaced, for example.
The only reason I can see for what looks like oxide around his hex. connections is that once you have an external leak, metal is going to corrode as there is an endless supply of O2 to overcome the reducing chemicals in the coolant. Corrosion guaranteed.
So, after all this, I have yet to see what could possibly induce a stray current in the hex. of a PROPERLY constructed engine without glaring electrical problems. PROPERLY being the key word here. There are an unlimited number of elecrical problems you could introduce here to cause a stray current problem.