If there's a way to over engineer it, y'all are sure to find it.
A tee in a vent line won't allow any ambient air to ventilate the tank, air will only travel across the top of the tee between the two thru-hulls.
Adding/moving a tank fitting on any tank is actually pretty easy to do these days, thanks to a li'l doodad called the Uniseal
UNISEAL Uniseal Instructions It will NOT leak! And is also VERY inexpensive.
All you need is a hole saw, a piece of pvc pipe that will become the new tank fitting, and a threaded plug and some teflon tape to plug and seal the old tank fitting--all of which are available from the plumbing section of any decent hardware store.
If the vent line can be short enough--<5', straight, and limited to rise that doesn't exceed 45 degrees, a single 1" vent should be enough to get the job done. "Vent" thru-hulls are only available in 5/8"...but a "vent" thru-hull defeats the purpose of a larger shorter, straighter vent line anyway. Use an open "bulkhead" thru-hull...that will allow you to backflush the line to make sure the vent line stays open.
Otoh, it the tank so low in the bilge that the vent line has to be long and vertical, a second vent line prob'ly won't help...in which case, aeration is the best solution. As an absolute LAST resort in a system that's so poorly designed that PREVENTING odor is impossible, a vent line filter to trap it may be the only answer.