LDM,
Not all metals rust. The correct term is corrosion. The toe rail is aluminum, so no rust. As Bill Ross pointed out, aluminum corrosion creates the white power film you are scrubbing off. Bill points out a couple of reasons why you may be seeing corrosion, and some corrective steps.
One additional tip: If you are using any kind of metal to scrub, like steel wool, you may be exasperating the problem. Fine particles of the scrubber will be embedded into the aluminum causing additional dissimilar metal corrosion.