I could very well be wrong, but I always thought all-chain was better than chain to rope. Most big, expensive boats I see, cruising around, use all chain. I just assumed, because of the weight, that all-chain provided a straighter pull on the anchor. And, chain last longer - less fear that your rope is at end of life, and might part.
We use a snubber - only about 10 or 12 feet from the cleat to the hook. I don't recall the size, maybe 3/4", three-strand nylon. I made it maybe 15 years ago, so it's probably due for replacement (!), but if it parts it won't be a disaster.
So, what's better? I say chain. Straighter pull on the anchor, and much longer service life. And, less expensive, long term, if you are replacing your nylon rode ever five years. I just priced both, 5/8" nylon is $1.49/ft., 5/16" G4 chain is $3.40/ft. (at Defender). So, for a little more than double, you can have chain.
I wouldn't do chain without a windlass, though. If you're hauling by hand, I think rope is the answer.