The trick on the small 1 lb ones is to put the empty in the
freezer for about an hour. My cost to refill them is $.25.
Leave your big tank in the direct Sun. The vapor pressure is big time different then.
I get about 3/4th a pound on each refill.
Tip: All LPG tanks are only filled to ≈80% anyway, you have to leave a vapor space to use the Vapor to burn only.
Jim...
PS: You can get more fill by putting the partial filled one in the freezer again.

But I found it wasn't worth the effort and time to do it for just a little more.
PSS: I fill about 4 empties at the same time. No biggie then.