Need concern over Iithium battery charging of device batteries?

Jul 27, 2011
5,116
Bavaria 38E Alamitos Bay
I'll be charging a Li power pack to service a portable on-board device using a 100 watt solar panel every couple of days for two weeks. I'll have a special encapsulating Li battery fire extinguisher aboard as well. Need I think harder about this or not to worry?
 
Jan 11, 2014
12,273
Sabre 362 113 Fair Haven, NY
There are some ifs here.

Are the batteries LiFePO4 batteries or some other chemistry?
Is there a controller for solar panel so the battery is charged correctly?
Are the devices from well known and respected brands?

Overcharging or charging at too high a voltage can cause the battery to go into thermal runaway, that is different from the usual fires we see that are oxidizing. Improper charging, poor design and construction, and limited or no ability to dissipate heat contribute to the problem. Some chemistries are more prone than others.
 
Jul 27, 2011
5,116
Bavaria 38E Alamitos Bay
The battery and solar charger are sold as a compatible set, where that compatibility includes the separate device to be charged. So, for the moment, I'm assuming that the charging is regulated. Of course, I'll confirm that before shoving off. It is LiFePO4.
 
Jan 11, 2014
12,273
Sabre 362 113 Fair Haven, NY
The battery and solar charger are sold as a compatible set, where that compatibility includes the separate device to be charged. So, for the moment, I'm assuming that the charging is regulated. Of course, I'll confirm that before shoving off. It is LiFePO4.
Those are good signs.
 

dLj

.
Mar 23, 2017
3,835
Belliure 41 Back in the Chesapeake
I'd say you are safe. The only thing I'd caution you on, be sure to not deplete the batteries below whatever that systems states. I did that with a different but similar system and then the thing would never recharge...

dj
 
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Jan 11, 2014
12,273
Sabre 362 113 Fair Haven, NY
I'd say you are safe. The only thing I'd caution you on, be sure to not deplete the batteries below whatever that systems states. I did that with a different but similar system and then the thing would never recharge...

dj
Also, LFP batteries do not like to be stored for long periods in a fully charged state.
 
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Jun 11, 2004
1,700
Oday 31 Redondo Beach
I probably wouldn't leave it charging when I was away from the boat.

You of course don't have to answer this but is the portable device a CPAP machine?
 
Dec 28, 2015
1,886
Laser, Hunter H30 Cherubini Tacoma
I'll be charging a Li power pack to service a portable on-board device using a 100 watt solar panel every couple of days for two weeks. I'll have a special encapsulating Li battery fire extinguisher aboard as well. Need I think harder about this or not to worry?
the extinguisher (I'm going to assume it is F500) is as effective as a BC extinguisher.......worthless. If they were, every fire department capable of proving the technology would have one on every unit. There are a lot of snake oil products out there due to new technologies. We see them routinely in the fire service. Your best tactic is to throw it overboard if you can safely do so.
 
Jul 27, 2011
5,116
Bavaria 38E Alamitos Bay
the extinguisher (I'm going to assume it is F500) is as effective as a BC extinguisher.......worthless. If they were, every fire department capable of proving the technology would have one on every unit. There are a lot of snake oil products out there due to new technologies. We see them routinely in the fire service. Your best tactic is to throw it overboard if you can safely do so.
It’s an E-FireX (1 liter) extinguisher. Kind of a new technology it is advertized (efirex.com). We’ll also have a small, high-temp suppressor bag with 2000 deg. F- resistant gloves. Put the thing in the bag and throw it overboard, if it comes to that. :biggrin:
.
 
Jan 11, 2014
12,273
Sabre 362 113 Fair Haven, NY
I did not know that. The device will be run everyday for several hrs.
Over night or for a few weeks, not really an issue. Put it away for the winter fully charged and it will lose capacity. That's why LFP batteries are always shipped from the factory at a 30-50% SOC.
 
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Dec 28, 2015
1,886
Laser, Hunter H30 Cherubini Tacoma
It’s an E-FireX (1 liter) extinguisher. Kind of a new technology it is advertized (efirex.com). We’ll also have a small, high-temp suppressor bag with 2000 deg. F- resistant gloves. Put the thing in the bag and throw it overboard, if it comes to that. :biggrin:
.
Sorry, its all BS (the extinguisher and the bag). The extinguishing agents on the market for lithium fires have shown no additional advantaged over using water. This means it does little to nothing with a larger battery pack run away. Current primary tactics for these incidents is separation and letting it burn. If the pack gets to a run away condition there is little to no way you will be getting anywhere near close enough to pick it up, place it in a bag and throw it overboard. This is due to heat and, way more of a issue, the gases and vapors being produced. Battery bags are also BS unless they are the ones used and approved by the NTSB and those ones are large but made for very small batteries. Its all about the bags ability to contain the hazards. They have to be a lot larger than the actual battery to do this. Most (read this as almost all) devices you see advertised for lithium technology (both ion and iron) are money grabs. A exception is containment products using Cell Block. Its kind of like a oil absorbent for lithium battery gasses/vapors. You should see what the BS manufactures are pushing in the fire service. Its laughable. The good thing is the technology you are using is not ion, its iron. A lot more stable but they are way more reactive with water, especially salt water.
 
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Jul 27, 2011
5,116
Bavaria 38E Alamitos Bay
If the pack gets to a run away condition there is little to no way you will be getting anywhere near close enough to pick it up, place it in a bag and throw it overboard. This is due to heat and, way more of a issue, the gases and vapors being produced. Battery bags are also BS unless they are the ones used and approved by the NTSB and those ones are large but made for very small batteries. Its all about the bags ability to contain the hazards.
Frankly, I had my doubts about that part as well. But this is a “small” battery; 8 1/2 x 6 x 1 1/2 in. Yet, if it caught fire on the boat below decks, it would pose a BIG PROBLEM. Especially if we had to run away to avoid caustic air and could not approach it. I take from your comments that those Kidde ABC extinguishers from WM might not prove effective on most fires if they got going. I’m willing to put an actual (real life) bonafide extinguisher on the boat and see to its periodic servicing, etc. Are there decent brands or general types out there to select from?
 
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Jul 27, 2011
5,116
Bavaria 38E Alamitos Bay
So, I take it that the risk of fire during charging or otherwise is less, may be considerably less, for lithium iron batteries, than lithium ion ones. Which makes sense if people are going to substitute lithium batteries for lead acid ones. So, maybe there’s no real concern here. I don’t know much about lithium battery useage on boats, etc., clearly. Everything on mine runs off of my Pb-acid banks, or separate deep-cycle, including my little electric trolling motor. The bag you mention seems directed to the ion versions.
 
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Dec 28, 2015
1,886
Laser, Hunter H30 Cherubini Tacoma
Frankly, I had my doubts about that part as well. But this is a “small” battery; 8 1/2 x 6 x 1 1/2 in. Yet, if it caught fire on the boat below decks, it would pose a BIG PROBLEM. Especially if we had to run away to avoid caustic air and could not approach it. I take from your comments that those Kidde ABC extinguishers from WM might not prove effective on most fires if they got going. I’m willing to put an actual (real life) bonafide extinguisher on the boat and see to its periodic servicing, etc. Are there decent brands or general types out there to select from?
BC extinguishers are perfectly fine for most needs on boats if you are able to get them under control during their incipient phase. Once things get going they can be impactful but the environment tends to dictate you leave and they become less impactful. Offensive actions during the intitial phase of the fire (building) and defensive actions to get you out with little intent to put it out. The larger the better and tactically placed is my recommendation. Don't place them next to the stove or engine. Place them at exit points and in sleeping areas to fight your way out. Putting them next to the place most possible to catch on fire does nothing when you can't get to them. A access port to the engine compartment is very tactical allowing the discharge of extinguisher without exposing you to the BTUs and toxic gases. Lithium Ion batteries pump out a ton of heavy metals and concern able levels of hydrogen cyanide.
 
Dec 28, 2015
1,886
Laser, Hunter H30 Cherubini Tacoma
So, I take it that the risk of fire during charging or otherwise is less, may be considerably less, for lithium iron batteries, than lithium ion ones. Which makes sense if people are going to substitute lithium batteries for lead acid ones. So, maybe there’s no real concern here. I don’t know much about lithium battery useage on boats, etc., clearly. Everything on mine runs off of my Pb-acid banks, or separate deep-cycle, including my little electric trolling motor. The bag you mention seems directed to the ion versions.
Its my understanding that lithium iron chemistry is more stable and less susceptible to heating and failing during charging. Once they get going, the same challenges apply.
 
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Likes: jssailem
Jul 27, 2011
5,116
Bavaria 38E Alamitos Bay
Sorry, its all BS (the extinguisher and the bag). The extinguishing agents on the market for lithium fires have shown no additional advantaged over using water. This means it does little to nothing with a larger battery pack run away. Current primary tactics for these incidents is separation and letting it burn. If the pack gets to a run away condition there is little to no way you will be getting anywhere near close enough to pick it up, place it in a bag and throw it overboard. This is due to heat and, way more of a issue, the gases and vapors being produced. Battery bags are also BS unless they are the ones used and approved by the NTSB and those ones are large but made for very small batteries. Its all about the bags ability to contain the hazards. They have to be a lot larger than the actual battery to do this. Most (read this as almost all) devices you see advertised for lithium technology (both ion and iron) are money grabs. A exception is containment products using Cell Block. Its kind of like a oil absorbent for lithium battery gasses/vapors. You should see what the BS manufactures are pushing in the fire service. Its laughable. The good thing is the technology you are using is not ion, its iron. A lot more stable but they are way more reactive with water, especially salt water.
Well, I did the cruise to Santa Cruz Island and we used the LiFePO4 battery to run our device; yes, a CPAP. Altogether, 17 nights on the boat: 7 in harbor; 9 on the hook, and one on a mooring can. Recharged battery daily using a 100-watt solar charger or shore power.. The battery is charged inside the 2000-deg tolerant bag. The bag contains the fire, if it occurs, long enough to pitch the whole set overboard. I think there were gloves to use as well. Interesting system. The solar panels can charge from 40% to 100% in less than 2 hr in good sunlight. So, it’s a relatively brief time to remain watchful.

There was pretty discouraging weather at the northern islands the first 7 days so we did not depart our anchorages at Catalina Island for Santa Cruz Island until Sept. 13. We had one night there at Little Scorpion before NOAA issued a gale warning (40-45 kt) for our adjacent forecast zones that sent us packing into Channel Islands Harbor (19 n.mi. distant) where we stayed two nights. Then one night at Ventura Harbor, and two at Santa Barbara Harbor (SBH). Returned to SCI across the East Santa Barbara Channel from SBH (during which where we lost the autopilot), anchoring one night at Prisoners under a SCA , then to Little Scorpion one night, then to Cabrillo Beach Anchorage in San Pedro Bay the last night following a 70 n.mi. motor in calm seas. Back into the slip yesterday. Not much sailing accomplished . Good to be home.:)
 
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