My opinion and another idea
RedHead78,
If you tried the hot rag on your pipes and have no smell they are not permeated.
A clogged vent would not allow you to pump the waste out of your head into the holding tank, since there would be nowhere for the displaced air to go.
You do not need or want a vented loop on your head discharge since it goes directly to your holding tank, per your diagram.
If you have validated that have no leaks in your plumbing or tank and the smell is not from your bilge there is only one remaining issue.
When you pump you head with salt water or brackish critters get caught under the bowl
in the lip. Pouring water or other concoctions in the bowl at this point will not kill all of the little creatures that have gotten caught and will die and dry up under the lip of the bowl.
What many owners and some manufactures have done is tee the head intake into the head sink drain. This allows you two options.
1. Keep the head sink thu hull closed and use fresh water in the sink for all flushing.
2. or….. put a stopper in the sink, open the thru hull for the head sink and draw sea water for all flushes EXCEPT the last one of the day or weekend. Before you close up the boat put fresh water in the sink with the thru hull closed, pump the head drawing water from the sink thru your head, this will clean all of the head and flush any remaining critters in the holding tank.
Try searching the archives, its full of Peggy Hall's words and years of wisdom.
Steve