You're kind of on the right track; the mast pre-bend and the shape of the luff of the sail need to match for optimal performance. And also correct, rigs with in-mast furling have mainsails that are typically cut with a straighter/flatter luff to match the fact the that the mast (typically) has less pre-bend to help the sail furl.
Now, 'twist' is the vertical shape the sail takes on when the vang is eased. It allows the top of the sail to fly correctly in the greater windspeed aloft. The sailshape created by a miss-match you describe will not effect this. You're more likely to see the corners of the sail pulled tighter, with diagonal wrinkles created. Taking the bend out will actually give you MORE (fuller) shape, not less.