@MikeHoncho Thanks for the reminding us that diesel is not as safe as we might to believe. It piqued my interest so I read up on the explosive properties of diesel. The Lower Explosive Limit (LEL) of diesel is 1% and the upper level is 6% according to
OSHA. Below 1% by volume diesel will not ignite and above 6% it will not ignite.
Curious about what 1% would look like in my engine compartment, I calculated the rough volume at 41,472 in3.(about 2'x4'x3' = 24 ft3). A fluid gallon has 231 cubic inches. If my math is correct (and sometimes it is off) it would take about 1.79 gallons vaporized to reach a 1% level. (414.72/231= 1.79). That is quite bit of diesel.
Meanwhile, with the diesel running at cruising speed (using
@Ralph Johnstone's calculation) the engine is consuming 31.42 ft3 of air per minute. In my engine compartment the air is being changed every 45 seconds (24ft3/31.42ft3 = .76).
If my logic is correct the engine would have to vaporize more than 1.76 gallons per minute to reach a 1% level. That's a lot fuel to vaporize. In order to attain that rate the injector pump would have to fail and spray diesel on the exhaust manifold or a very hot alternator. And then it would need an ignition source.
I think a fire or explosion from diesel inside our small engine compartments with small diesels is a low probability event, however that does not negate the possibility. Promptly dealing with and fuel leaks and a clean bilge and engine compartment might well be the best preventative measure. Incidentally, propane gas leak sensors are also sensitive to diesel vapors and will sound an alarm.
The more likely scenario for diesel explosion might be while fueling a near empty tank on a hot day. Vapors in the tank could reach explosive levels and a spark from static electricity generated while fueling could trigger an explosion. Boats with twin diesels of a larger hp might be more problematic as one diesel could spray fuel onto the other causing the ignition.
Another issue worth considering is how a small fire onboard could ignite the diesel and cause the fire to rapidly expand.
Note, the calculations here are rough back of the napkin calculations and not meant to be definitive. The goal is to put the issue Mike raised in context, yes it is a concern, no it is not as much of a concern as gasoline, propane, and other flammables onboard. Almost all of the organic solvents we use, Acetone, mineral spirits, alcohol, etc. are combustible and explosive at some level. Some are safer than others.