This should help
You're asking about the Raritan ElectroScan (newest version, renamed, of the Lectra/San, which has been around since the 70s.). Spending some time with the literature and instructions for it should help you understand how it works You'll find those here:
http://www.raritaneng.com/products/waste_treatment/electroscan.htm
From this page, go to the Promo Sheet, and then the owners manual...you see those listed on the left side of the page. Unless your toilet uses onboard pressurized fresh water, you don't need to worry about the salt tanks.
As for where you can use it: in any US waters that are not specifically designated "no discharge" (hold for pumpout only). On the east coast, that would be just about all coastal waters between the FL Keys and New England..and everywhere in the Gulf of Mexico except the FL Keys and Destin Harbor. Inland fresh water lakes and rivers are a different story...the discharge of treated waste is legal on most rivers, but not all...most inland lakes and the Great Lakes are "no discharge."
So whether to install a treatment device or a bigger tank really depends on where you plan to cruise in the US. If in parts of the country where treatment is legal, I highly recommend it!