Info on blisters and the curing temp required (80 degs. C)
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Here's some info on the chemistry problem. Not sure if this applies to the resins used in your boat but it is a pretty logical summary. Not too technical with chemical equations and such but puts it in layman's terms easy to understand. Happy reading. I searched on gelcoat blisters uncured resin to find this.[/FONT]
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[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.1. "Osmosis" is in reality not an adequate name.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]In the sixties a leading yachting magazine wrote an article about a mysterious "illness" hitting FRP boats. In short it said, that intruding water caused an "osmotic pressure" which de-laminated the FRP layers. The theory was repeated by a lot of other magazines and created the now universally accepted name "osmosis".[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The basis for these articles, most likely, was the results of core sample testing provided at that time. In all samples from blistered hulls, the tests revealed a much higher content of WSM:s (water soluble materials), glycol and free styrene than normal for a sound laminate.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]With the laboratories lacking practical field experience from the problem, an incredibly long-lived but false theory was introduced, that the gel coat blisters are formed when the concentrated solution of WSM:s and glycol in the laminate absorbs water through the gel coat by "osmosis".[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The term „osmosis" was born and spread all around the world![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]In fact there is practically no osmosis involved in the process and it certainly does not create any delaminating pressure.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Today, with the field knowledge that gallons of the substances in question can be found within a few m² laminate, it is easy to understand, that the substances found are created by the process and not the opposite.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Incredibly enough some core sample testing laboratories still report findings of "substances which might cause osmosis damages" and thus keep the myth alive.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Also the myth has been used by the boat industry in order to make the public believe in a "minor" problem caused by a few careless boat builders![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]As late as 1988 a couple of well known boat builders wrote articles in English an Scandinavian yachting magazines, telling that the "osmosis" problem itself was a myth and really did not exist!![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.2. "Osmosis" reason: Hydrolyse of uncured resin![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Five years of intense laboratory research and practical tests on hundreds of samples from cut up "osmosis" hulls as well as on whole hulls gave us quite a new view of the reasons for and the damages formed by the "osmosis" plague.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The main reason for the "osmosis" was found to be, that boat hulls are too large to be post cured within an economical range.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Post curing at 80ºC after the initial curing in the mould is needed for polyester resins to achieve a total curing of all the polyester chains.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Instead of post curing, usually laminate dimensions are increased to compensate for the 10-15% lower strength due to the missing post curing.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]There have been few considerations about the chemical consequences![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]A not post cured laminate contains as much as 10% styrene enclosures with a "skin" of uncured polyester between them and the cured polyester.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Further many of the cured polyester chains have no curing links in the ends, so called "dangling chains"[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.2.1. The styrene enclosures:[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The "osmosis" begins, when under certain circumstances moisture enters into the styrene enclosure. This[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]water in combination with the styrene hydrolyses the surrounding uncured polyester.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The large polyester molecules split into a multitude of smaller acid, alkali and glycol molecules which need more space than the original ones. This creates a pressure which forms blisters in the elastic gel coat.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]A not commonly known effect of the "osmosis" process is, that the very small alkali molecules follow the inward capillary movement of the moisture and cause a loss of bond between fibreglass and polyester.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The result is a loss of strength in the hull of 20-30%, and abnormal damage can be caused by the slightest grounding.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.2.2. The "dangling chains":[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The dangling chains are the main reason for many "osmosis" recurrences after common treatments.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]As mentioned before, acid e.g. pthtalic acid is formed during the hydrolysis process. The acid is also absorbed into deeper laminate layers and will stay there despite any kind of normal washing and drying.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]When pthtalic acid molecules come into contact with cured polyester chains attached with "dangling chains", the total chain breaks up into styrene and uncured polyester.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The resulting mixture is extremely sensitive to hydrolysis and needs small amounts of moisture to restart the process.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.2.3. Enough water always available[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Beside from moisture entering from inside condensation and the bilges, even the most successful drying will leave at least 0.5% moisture in the laminate, enough for severe hydrolysis to proceed in spite of high quality watershield systems![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Especially in large hulls with heavy roving layers and/or sandwich core, such a huge amount of polyester can be hydrolysed that several m² of one or more laminate layers are no longer bound together. After a short time this "de-lamination" fills with gallons of an acid/glycol/water mixture.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]If left unattended, in a few years the laminate will have lots of areas where only the gel coat over wet soft fibreglass is left! (See pictures)[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Very often no telltale blisters will form as the pressure is evened out in the de-laminations.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.3. Uncured resin in laminate can be hydrolysed.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]To enable an "osmosis" process to start, molecules of uncured polyester, styrene and water must come into direct contact. Fortunately, water cannot affect properly cured polyester.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]However, when moulding FRP, there are a lot of more or less uncontrollable circumstances, which cause excess styrene to be trapped inside the cured material.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Such styrene enclosures are always separated from the cured surrounding by a skin of not cured polyester resin.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.4. Why does the "osmosis" not start in all FRP hulls?[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Most "experts" explain that "osmosis" is merely a result of faulty manufacturing. Regarding boats, water is supposed to enter into the hull by diffusion and capillary effects and then by osmotic force be brought into the enclosures.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Not accepting this for a truth, the HYAB organization spent many years analysing "osmosis" hulls for some substance that could be the trigger of the process.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Finally in 1993 the answer was found.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.5. Trigger found: fibre strand penetrating enclosure.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Finally in 1993, studying an old laboratory report about "leaching"(very similar to "osmosis") in FRP roofing elements, a plausible theory was found. Even if not practically tested, it gave reasonable answers to earlier pecularities.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The report ascertained that there can be no osmotic force between pure water and pure styrene but that water might enter along a fibreglass strand piercing the styrene enclosure![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Practical tests performed by HYAB have proved this theory to be valid.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.5.1. Enclosures do not normally form around strands.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The tests showed, that except when damp fibreglass is used (in such cases it is well known that "osmosis" alwaysoccurs), it isnot normal that enclosures are formed around a fibre strand.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Due to the high surface tension of the uncured resin, the "balloon" around the styrene enclosure is deformed by the surrounding glass fibres but seldom pierced, especially where no woven roving is involved.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.5.2. Many FRP hulls have no trigger type enclosures.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]A great many FRP boats have no such fatal enclosuresand will consequently not develop "osmosis".[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The fibre strand being "the trigger" solves the other confusing fact, that "osmosis" never affects the gel coat.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]This material always has lots of small styrene enclosures just under the surface close to the water. According to any other explanation the "osmosis" would have started there![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.5.3. Small size hulls less effected than the big ones:[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Looking at the published estimations of "osmosis" among the total fleet, one can clearly see that the percentage of boats affected increases proportionally with the average hull size. Since the 15% reported in 1980 the figures have now reached an estimate of 40%[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The HYAB research, performed at 5 test centers in different parts of the world, now presents a more exact picture of the "osmosis" frequency:[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Hull size < 25´ = 5%, 26´- 40´ = 15%, 41´- 50´ = 30%, 51´- 65´= 60%. As to bigger hulls, so far the HYAB research covers only 6 yachts, all of which were affected.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Regardless of size, hulls containing woven roving mats of over 600 g/m² have a very high "osmosis" frequency. If they also have core material reaching down under the water line, the frequency seems to be 100%![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.6. Construction faults influence process severity.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]If triggers are present, the number of such styrene/uncured polyester enclosures and the situation determin the speed of the process. If no triggers exist, no "osmosis" will develop regardless of enclosure amount.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Below some of the most common enclosure sources are described.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.6.1. Enclosures emitted from the curing of the gel coat.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Most, not to say all FRP boats made in moulds without post curing have styrene enclosures in the first two layers of FRP.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The enclosures are caused by styrene emitting from the gel coat, which is not fully hardened when the first layers are applied.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]A laminate with up to 5% styrene/uncured polyester and dangling chain molecules in the outer laminates and very few enclosures in the inner laminate can be considered as top class.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The existence of "trigger" enclosures is pure chance, which no boat builder can be blamed for![/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]If no woven roving exists in the laminate, an eventual hydrolysis process will mostly be limited to the outer 2-4 layers during at least five years from when the first blisters were noticed.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]A peeling and "dry and shield" repair might stop further hydrolysis and blistering but will not restore the loss of bond between fibreglass and resin.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Even in a top class laminate this causes at least 15% less structural strength.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.6.2. Styrene enclosures from disturbed curing.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Disturbed curingis another cause of styrene enclosures. Normally the curing proceeds uniformly right through the material by styrene crosslinkingthe polyester molecules and excess styrene evaporates.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]A number of factors can disturb this process. In connection with "osmosis" the most important ones are:[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Draught over the curing surface causes uneven curing from the surface downwards.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]This traps some of the excess styrene inside the FRP and causes styrene enclosures all through the laminate.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Labour welfare acts in the eighties, demanded improved ventilation. Many ventilation systems were built up with suction hoses arranged over the moulds.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Some manufacturers had years of production where a great number of boats "inexplicably" developed "osmosis".[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Later it became evident that the ventilation hoses were placed a foot too deep into the mold and thus caused fatal draught over the surface.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Too much accelerator, re-accelerated resin or too little catalystforce a small part of the curing polyester to "spit out" the styrene meant for the curing during the gelling stage.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The thus uncured polyester again forms a bubble around the styrene and is accordingly enclosed in the cured FRP.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.6.3. Enclosures caused by moist fibreglass.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Use of moist fibreglass in the productioncreates the worst styrene enclosures.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]The fibres then becomes almost totally coated with styrene and uncured polyester. Takes a long time to form gel coat blisters. Often these are low and as big as hands.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]Can also occur on deck and cabin roof areas.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]1.6.4. Styrene enclosures are a property of the material.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]As mentioned before, post curing at 80°C will rid the laminate of such enclosures when the uncured polyester uses part of the styrene to cure and excess styrene evaporates.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]It has been practically impossible, within economical limits, to mould FRP boats from polyester types used before 1990 entirely without styrene enclosures.[/FONT]
[FONT=Arial,Helvetica,Geneva,Swiss,SunSans-Regular]It is just a property of the material like metal corroding or wood cracking. No one can be blamed for this except those who used damp fibreglass or reaccelerated resin.[/FONT]