cable sizing
The cable sizing depends on distance and expected amperage. Long wire runs need larger wire to avoid DC voltage drops, but for battery-combiner cables this is not a problem.
If you are just combining these 2 batteries together to extend your usage time, and not adding any load to your existing system, then you can use a same-or-larger diameter cable to hook your batteries together, but that cable should not be smaller than your original battery cables.
Check that the battery wires running to your panel and big red switch are 4AWG. If they are larger, you should match their size when combining the batteries.
If your adding a small invertor to power a TV etc., you will connect it directly to the battery bank. Invertors pull a lot of amperage from the batteries, thats why its important that the battery-combiner cables are matched to your heaviest expected load. For example, if the invertor recommends 2AWG running to the battery, then you should also have 2AWG for the combiner cables. ( example - AC invertor of 1000 watts AC = 83 amps DC, at 12v. Your DC panel probably pulls 30 amps max with everything on )
Lastly, make sure the original cables are boat cable ( like the description of your new 4AWG wire ). If its not marine wire and its not 'tinned' then consider switching it out, especially if your in salt water.
I reccommend you buy a book or two from your local marine store if your plannng any upgrades to your electrical system. Older boats designs did not have all the 21st century toys we have now.