Skipper John, it all depends on what position your selector switches are in. If the engine selector switch is in position 1+2 then the starting battery is in parallel with whatever battery or batteries are selected by the main selector switch. If you want to measure the voltage on your starting battery, you can move a wire.
Unscrew the switch panel (after disconnecting your batteries of course) and move the small gauge (orange on my boat, not purple) wire from position 2 of the Main Battery Selector switch to position 1 of the Engine Selector switch. The battery condition meter will show the starting battery voltage provided the Engine Selector Switch is in position 1 (and the panel is powered by the Main Battery Selector switch.)
If you want to be sensible, move the other small gauge (orange? Purple?) wire from position 1 to the C terminal on the Main Battery Selector switch. Then, when the Engine Selector switch is in position 1, one position of the battery condition meter will give the voltage of the starting battery and the other will give the voltage of the house batteries as selected by the Main Battery Selector switch.
If you want to just use a hand held volt meter, make sure both those switches are OFF. Otherwise, some or all of the batteries will be connected in parallel.
For the record, our boat is a 2018 Catalina 315, hull 61.