Many ways to skin a cat
Thyme, you probably can do that. One question is what is your energy budget? On the one hand, combining all four golf cart bats into one series/parallel bank will give you longer life because you will discharge the combined bank to a lower extent, and that gives the batteries longer life. OTOH, if your energy budget and charging allow you to recharge and alternate banks without going beyond a 30% discharge depth (for two batteries) then two banks gives you some redundancy. If you haven't bought the batteries yet, options to consider are just using 6 2.2v commercial cells, to make one industrial battery. Or, using two 12v batteries of larger size, if you can lift & stow them.<G>On wiring...I would expect you could use your existing battery switch for the two deep cycle banks (assuming that's how you want to go) and connect the SLI battery *just* to the starter and one charger lead--so it can only run the starter, and the charger charges it whenever the engine is running. That should be all you need to isolate and charge it.Instead of installing more complicated switches, etc., to allow your house bank to be used for emergency starting, you can buy a top-quality set of jumper cables and keep them stowed for that purpose, too. A bit more flexible.DO make sure those batteries are fused (not breakers) right on the battery, and the series/parallel bank is fused once for each series bank as well, preferably with a way to separate them reasonably quickly in case you find one bad battery (or one bad cell) trying to pull all four down. Cable quality, matching cable lengths, and clean connections all should be the rule for that kind of setup.