No way you can have a one-way vent block...
.If the tank is pressurizing, I suspect that you have a partial blockage--possibly a kink, or something has gotten into it. You may have cleared it when you filled the tank to overflowing with water. Fill it with water again, and this time be standing close enough to the vent while it's being pumped out (not during a macerator dump-out, 'cuz a pumpout has much stronger suction than a macerator)...if the vent's ok, you should be able to hear air going into it as the level in the tank drops...and it should get noisier when the tank is empty. In case the vent isn't open sufficiently, put someone else next to the tank to watch the level (if it's plastic) or (if aluminum) the sides of the tank to make sure the pumpout isn't trying to collapse the tank. In a metal tank, a small amount of flexing as the tank empties is normal...watch for signs of a real strain.If the system doesn't have a y-valve, only a wye or tee fitting, in the pumpout line, your macerator WILL sound different with the deck fitting cap off...because it's mostly sucking air instead of the tank contents. The deck fitting has be closed, or you can't empty the tank. And that's another thing to check: You know how much the tank holds...after you think you've emptied it, put water back into it from a container that will allow you know how much you're putting in the tank before it overflows. If it's not close, the tank isn't emptying.