Ok, I think I finally got it figured out.
1. First you have to follow the instructions that I posted above to add a new system name to the Stations List (View>Station List>New). The name can be anything other than "HAM" or "SAIL". Once you have the System Name in place, select the new system and click on settings.
2. Next you have to add the stations to the new system, using the call sign as the name of the station. While still in the Station List screen, simply highlight the system name and click on New. A window will pop up and ask for the call sign of the new station. Add the new station call sign and hit OK. This will add the call sign to your new system.
3. While on the new system and have the station list expanded to see all the stations, highlight the call sign and click on Settings. This will bring up a window where you can put in some personal data regarding the call sign, and make a frequency list. List the frequencies that you intend to use in the big box to the right. Click on ok when done, and you can list multiple frequencies for each call sign.
4. Save all your settings. Click on Tools>Options>AutoAnswer and make sure the Accepts Incoming Connects box is checked. When frinished close Airmail down completly.
When you restart Airmail, click on the Terminal window. Click the arrow on the drop down menu to the left, and you will find your e-mail system AND your new system. Select your new system, and in the drop down menu in the middle, you can select the station. The last drop down menu on the right contains the frequencies that were listed with that station. And you are ready to go!
Ps. These instructions apply to the latest version of Airmail2000, version 3.4.034