I've not converted a black water tank to a diesel fuel tank, but I have a three diesel fuel tank system, and I've converted all my heads to composting heads - I have two heads.
First, I am going to confess that I am now a staunch supporter of composting heads. I have been amazed at these heads, I put in this new one called OGO but I'm sure they are all excellent. If you are interested in more information on that aspect, just ask...
As to the diesel tank - my system is three fuel tanks; two saddle tanks, one on each side of the boat at the same level and a third tank I call a pony tank that sits below these two tanks and is where my engine pulls and returns fuel into. This is done such that on no matter what heal, nor sea state condition, the engine is never starved for fuel. The three tanks work as an integrated system. It's simply how my boat was designed.
You will have to look at your levels and redesign your system with this new tank incorporated into the diesel system. I'm guessing that you will likely have to use it as an independent diesel tank as making it part of an integrated system as I have will likely not be possible. It will likely be an auxiliary tank. So you'll have to look at how you connect to your current system. Are you looking to be able to separate fuel sources once installed such that you could run from one or the other or are you looking to create an integrated system? Will you use this tank to pump fuel into your current tank? Will you use it as a feed tank for supplying your engine when running fuel off this one? Will you now pull from this tank for your engine and have your existing tank simply dump into this one? How will you run your vent line? Do you need pony pumps? You will have to decide those kinds of things.
I'd suggest make a diagram of your boat and the fuel system, both current state and then proposed future state. That may help you decide how best to do this. With a diagram, folks on here may be able to give better input.
I think it's a great idea by the way. So go for it!
dj