I agree, Donalex......
I've seen the situation you described, where a battery can't be charged at greater than its full-charge voltage:A bank of 24 Exide GU-33 cells, delivered dry to Egypt. We filled them with electrolyte - 15 gallons each! - and even open-circuit they went through an immediate discharge cycle and got quite hot. (I never quite figured out the chemistry of that, but it was consistent behavior for more than 100 banks). After letting them cool down, we measured the voltage at about 45vdc and hooked up the chargers - 2 rated at 400 amps each at 48vdc. Then we started charging, and pumping 800 amps in would only get the voltage up to about 47. We backed off to 400 amps (C/8), but even then the temperature would rise to 120F in about 30 minutes, so it took weeks to get a full charge in. Did I mention it was summer in the Sahara desert and there was no cooling in the battery room?Certainly if a battery is fully-discharged, you should charge it in isolation, but in normal usage, you aren't going to run into any problems by charging all your batteries at once. For starters, it's a MUCH more efficient way to go, since most alternators can put out much more current than a single battery can accept.Tom, I can't figure out what happened to your battery, but it's hard to figure that it happened overnight. First off, loss of water isn't from boiling, it's a chemical reaction called electrolysis, which occurs when there is excess current being put through the battery over and above what is needed for charging - this is 'gassing'. Boiling would give you water vapor, but what is being released from the battery is actually hydrogen and oxygen - if your battery had clear acrylic sides, you could actually see tiny bubbles (Aloha, Don Ho!) of hydrogen and bigger bubbles of oxygen.Secondly, 'dry' is a mis-nomer, because more than 25% of the liquid in the battery is sulphuric acid, and that doesn't go anywhere. However, the level in the cels probably sank below where you could see it.Finally, your battery might have charged up and be acting like it's OK, but it's doubtful that it is. You certainly exposed at least part of the lead plates to the air, which is a bad thing, and it sounds like you discharged it down to dead flat zilch, which is worse.Before you get into a situation where you MUST depend on that battery, I strongly suggest that you load test it. Most auto parts stores can do that for you, or you can charge it full, then discharge it into a known amount of load and record the voltages over time, then compare your results to a nominal curve. In many cases like this, a battery will charge to the right voltage and appear to work fine for a while, but its amp/hour capacity is actually a fraction of what it should be.The fully-charged, open-circuit voltage of your two types of batteries shouldn't be different (assuming that they are both in good shape) by more than a few hundredths of a volt.Cheers,Bobs/v X SAIL R 8Note: I made a mistake on the chemistry explanation (it's PBSO4, not SO2), but that doesn't effect the way the reaction works.
