AIR LOCK
you have an air lock. Either you will need to install a "bleeder valve" at the lowest possible spot in the system or sometimes if you take the hose off the water heater (from the engine) with the engine RUNNING just enough to let the air escape but not let all the coolant dump out,just pull the hose off to let the air escape and the pump push the water thur,it general take a couple of seconds,hold the hose at the fitting and maybe just pull the top of the hose off and leave it on the bottom so you can see the water flow. Not a hard job but you need to get the air out of they system, this will stop the overheating.