Two most common places for vent blockages:
1. The thru-hull...you may need to scrape it out with a screwdriver. If there's a screen on it, don't worry about destroying it...screens are just dust and dirt magnets, plus they corrode..you're better off without it. 2. The connection on the tank...even more likely if you allow your tank to overflow out the vent--hard to prevent when you're heeled if the vent fitting is in the wrong place (which it is on most boats), but if waste out the vent is your method of determing when the tank is full, you deserve far worse punishment than just a blocked vent. If cleaning out the thru-hull doesn't clear it, check the line for a kink...if there is none, remove the vent hose from the tank and clean it out. If THAT doesn't cure it, it's prob'ly gonna be easier to replace the vent line than it will be to clear a clog somewhere in it. Don't use the toilet again or attempt to pumpout again till you have cleared the vent..flushing the toilet against a blocked vent will pressurize the tank, which can have all kinds of nasty results--from a waste explosion back through the toilet to a cracked tank...pumping out against a blocked vent can put enough suction against the tank walls to crack the tank.