Trace the vent line from the tank to the hull...that's where the vent thru-hull will be. It'll prob'ly be exactly like the water and fuel tank vent thru-hulls, which makes it hard to clean out by blasting it with a hose because they're designed to prevent sea water from contaminating the fuel and water via the vent. 99% of vent blockages occur in only two places: the vent thru-hull or the other end of the vent line--that end of the hose or the vent fitting on the tank.So scrape it out...use a screwdriver blade, ice pick--whatever works. If there's a screen, knock it out...screens cause more problems than they prevent. If that doesn't result in a spew out the vent, you'll need to relieve the pressure before removing the vent line from the tank to clean them out...so open the deck pumpout fitting VERY CAREFULLY with a hose at the ready. Be sure you're UPwind of it! Scrape out that end of the vent line and the vent fitting on the tank...replace the vent line. If there's a filter in the vent line, remove it...once a filter gets wet--which can happen when a tank is overfilled or even due to heeling--the charcoal swells and blocks the vent...one of the reasons why vent filters aren't recommended for use on most sailboats.
One you've found the thru-hull, this would be a great time to replace the vent thru-hull with one you CAN blast out--an open bulkhead or "mushroom" thru-hull that'll let you prevent blocked vents in the future by sticking a hose nozzle against it and backflushing the line every time you wash the boat and/or pumpout.
--Peggie