Phosphate is being use in batteries now. LiFePO4 type. So they may act like the Cathode on a battery.
So the phosphates would draw Electrons from the Zinc, therefore making the Zinc sacrifice more than normal.
But they should not interfere with your testing.
I have this Probe...
Corrosion Reference Electrode: Corrosion Quiz
That comes with a proprietary manual on testing sequences. I called them and asked for a PDF file of their manual.
The owner said NOPE, since he is a certified ABYC electrician. So he is selling his knowledge too.
Here is what I suggest.
1) Record your testing volts and sea water temperature [I keep mine in a notebook for comparison ]
2) Drop the AgCl probe at the ≈ depth of your shaft Zinc and close to it.
3) Then test the shaft and wait till your meter stabilizes. [I have a alligator clip on a long testing wire to clamp on testing points] Next time on boat I will take a picture of my testing clamps.
4) If you have Zinc protection it should be close to the range on that chart above.
5) Disconnect shore power, see if the meter changes. No significant changes then you are not getting anything from the AC green wire.
Then proceeded to test any component on your boat, step by step.
One example noted that no problem until he turned on his radar. The radar transmission was not the problem but the radar supply circuit was bleeding.
I freaked out the first time I tested each of my bronze thru hull valves. I got -.470 V , [not right] until I realized it was my Lead-Antimony Keel I was reading.
My probe bought me a lot of...
Peace of Mind
Jim...