For several years I have tried PB Blaster, Marvel Mystery Oil, as well as SuperLube. I have applied it from the bottom shooting it to the top of the ball with the ball partially closed to trap the lube on top. I open and close the valves every time I leave the boat for more than a day- this has been my practice forever.
Nothing I have tried has worked. The only process that has freed up a valve has been to soak it in PB Blaster for 5-6 weeks, and even put in some On-and-Off acid-type cleaner. The On and Off needs to be a very brief application and then rinsed out before it can work on the ball coating. Perhaps this spring I will try to shoot some PB Blaster through a long tube to the top of the valves- I am resisting having to remove all of the hoses on the valves.