I'm glad you worked it out. I vaguely recall doing something similar on my C36 with Universal M25.
I was puzzled when I discovered my Tartan 3800 has a remote coolant tank with a pressure cap in addition to the default tank that is the water jacket exhaust manifold. The water heater is higher than the engine, in the port cockpit locker. near by, higher up, is a metal remote coolant tank, of about a gallon capacity, with a pressure cap and coolant overflow tank. There was nothing about this in the Westerbeke manuals or the Tartan owner's manual.
I called Hansen Marine Engineering in Marblehead, the regional Westerbeke distributor, and spoke with Bob Hansen. He told me that the remote tank was installed because it's nearly impossible to properly fill and bleed the system without it, the water heater being higher. He said all of the coolant service is done at the remote tank. The pressure caps are different pressure, with the one on the manifold being higher, typically 14 psi, and the remote tank at 7 psi (but check the caps, he advised, the pressure is marked on them).
Now I get it, having read of your troubles with this.