You need to lift the far end of the boom until it's pretty far up (probably more than half way towards vertical). Once you do you should be able to pull the boom away from the mast (in the upward direction that the boom is pointed) and it will disengage. Be sure to have the vang and sheet removed first. If your topping lift runs through the boom you should tie a messenger line to the end of the lift, then pull the topping lift out and tie the messenger line in place on both ends so it's ready to pull the TL back through in the spring.
That gooseneck (the two half ball shaped things on the mast) should be held in place by metal semi-circular clips. It looks like the clips were lost on yours, so when you pull the boom off the bottom half will likely fall away (and obviously end up in the water).
Replacement clips (and balls if you lose half) can be procured from Rig-Rite. I think it's the one at
http://www.rigrite.com/Spars/Isomat_Spars/Isomat_Booms/NB26_oldstyl_gsnk_assem.html kit NB1-5K for the whole thing, or NB1-6 for the clips.
Best practice is to store the balls and clips somewhere safe for the winter, then reinstall just before putting the boom back on.